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Baking soda will not keep your body free of toxins. It may help somewhat with your alkaline/acid balance (pH) and it can kill off some pathogens it comes into contact with, but that pretty much ends at the digestive tract, since baking soda itself is not absorbed intact into the blood stream (though an urban myth would have us believe that it is if we mix it with maple syrup – hogwash!).
To keep your body as free of toxins as possible, drink plenty of water and make sure that you pay attention to keeping your liver healthy and your bile ducts open and flowing. The liver is the body's primary toxin removal organ.
Items that are good for the liver and bile ducts include milk thistle, alpha lipoic acid, selenium, turmeric, beetroot juice and coconut oil.
Three items that help remove heavy metals from the body are cilantro, chlorella and parsley.
Pure cranberry juice and watermelon help keep the kidneys flushed out and healthy. The kidneys are the second most important organ for removal of toxins.
A third area of the body where toxins are removed is the skin. Thus it would be a good idea to keep your skin clean and scrubbed.
It's a toxic world these days, and taking extra measures to help your body clear out toxins is certainly a good idea.
EDIT: If you were previously told that fluoride does not accumulate in the body, you were fed some mainstream misinformation. That happens here often. Mainstream apologists do not want you to know about the dangers of fluoride, which is a mining by product that has been pushed upon an unwitting public under the guise of preventing cavaties. In fact, fluoride is quite dangerous and it actually damages teeth. Funny how the communities in the US with the fewest cavaties do NOT have fluoridated water.
For another look at the issue of whether fluoride accumulates, see: